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Research on Crops

 Dissipation kinetics and dietary risk assessment of chlorantraniliprole residues in/on garden bean (Lablab purpureus var. typicus) using ultra high-performance liquid chromatography 


DOI: 10.31830/2348-7542.2023.ROC-883    | Article Id: ROC-883 | Page : 113-118
Citation :- Dissipation kinetics and dietary risk assessment of chlorantraniliprole residues in/on garden bean (Lablab purpureus var. typicus) using ultra high-performance liquid chromatography. Res. Crop. 24: 113-118
S. PREETHI, K. N. RAGUMOORTHI, B. VINOTHKUMAR, V. BALASUBRAMANI AND D. KUMARESAN preethikaviprakash@gmail.com
Address : Department of Agricultural Entomology, Tamil Nadu Agricultural University, Coimbatore-641 003 (Tamil Nadu), India
Submitted Date : 12-10-2022
Accepted Date : 12-12-2022
Online Published:

Abstract

The aim of the study was to find out the dissipation rate of the chlorantraniliprole residues in garden bean pods.  Insecticides were sprayed at the farmers’ holding located at Naraseepuram, Coimbatore during the year 2022 (March to April), and the collected samples were processed and analyzed in the laboratory. An effective modified QuEChERS method was developed and validated to estimate the chlorantraniliprole residues in Ultra High-Performance Chromatography. Good linearity with R2>0.99 was achieved with the Limit of Quantification as 0.05 mg/kg. The relative standard deviation was below 5% for the recoveries obtained (93.30 to 97.91%). The residues persisted up to 10 and 15 days after treatment for recommended (20 g a.i./ha) and double the recommended doses (40 g a.i./ha), respectively. The half-life of chlorantraniliprole in garden beans was calculated as 2.18 days for recommended dose and 2.89 days for double the recommended dose. Intake of chlorantraniliprole residues through garden beans at either of the doses was found to be safe as the calculated Risk Quotient (RQ) was less than one.

Keywords

Chlorantraniliprole dissipation garden beans method validation risk assessment 

References

Anastassiades, M., Lehotay, S. J., Stajnbaher, D. and Schenck, F. J. (2003). Fast and easy multiresidue method employing acetonitrile extraction/partitioning and dispersive solidphase extraction for the determination of pesticide residues in produce. J. AOAC International 86: 412-31.
CODEX ALIMENTARIUS (2014). Accessed 04/07/2022. https://www.fao.org/fao-who-codexalimentarius/codex-texts/dbs/pestres/pesticide-detail/en/?p_id=230.
Hannig, G. T., Ziegler, M. and Marcon, P. G. (2009). Feeding cessation effects of chlorantraniliprole, a new anthranilic diamide insecticide, in comparison with several insecticides in distinct chemical classes and mode‐of‐action groups. Pest Manag. Sci. 65: 969-74.
Hoskins, W. M. (1961). Mathematical treatment of the rate of loss of pesticide residues. FAO Plant Prot. Bull. 9: 214-15.
Lahm, G. P., Cordova, D. and Barry, J. D. (2009). New and selective ryanodine receptor activators for insect control. Bioorg. Med. Chem. Lett. 17: 4127-33.
Lahm, G. P., Stevenson, T. M., Selby, T. P., Freudenberger, J. H., Cordova, D., Flexner, L., Bellin, C. A., Dubas, C. M., Smith, B. K., Hughes, K. A. and Hollingshaus, J. G. (2007). Rynaxypyr™: A new insecticidal anthranilic diamide that acts as a potent and selective ryanodine receptor activator. Bioorg. Med. Chem. Lett. 17 : 6274-79.
Mahalle, R. M. and Taggar, G. K. (2018). Yield loss assessment and establishment of economic threshold level of Maruca vitrata in pigeonpea. J. Food Legumes 31: 36-44.
Malhat, F., Abdallah, H. and Hegazy, I. (2012). Dissipation of chlorantraniliprole in tomato fruits and soil. Bull Environ Contam Toxicol. 88: 349-51.
Netwal, M., Choudhary, M. R., Jakhar, R. K., Garhwal, O. P. and Choudhary, G. (2022). Growth attributes of Indian bean (Lablab purpureus L. var. typicus) as influenced by bio-regulators and plant growth promoting bacteria. J. Pharm. Innov. 11: 1882-85.
NIN (National Institute of Nutrition) (2020). Accessed 04/07/2022. https://www. nin.res.
in/RDA_Full_Report_2020.html.
Pandit, T. R. and Dwivedi, S. A. (2021) A study on biology and management of spotted pod borer, Maruca vitrata (Geyer) in legumes. Biological Forum – An Int. J. 13: 01-09.
Paramasivam, M. (2021). Dissipation kinetics, dietary and ecological risk assessment of chlorantraniliprole residue in/on tomato and soil using GC–MS. J. Food Sci.Technol. 58: 604-11.
Paramasivam, M. and Bhuvaneswari, K. (2020). Dissipation kinetics, decontamination and risk assessment of chlorantraniliprole in okra and soil under open field condition using GC-MS. Int. J. Environ. Anal. Chem. pp. 1-13.
Purwanti, E., Prihanta, W. and Fauzi, A. (2019). Nutritional content characteristics of Dolichos lablab L. accessions in effort to investigate functional food source. In: 6th International Conference on Community Development (ICCD 2019) pp. 166-70. Atlantis Press. Advances in Social Science, Education and Humanities Research 349: 166-70.
Reddy, S. S., Reddy, C. N., Reddy, A. A., Rao, A. M. and Reddy, S. N. (2021). Dissipation pattern of flubendiamide 480% SC in Dolichos bean. J. Entomol. Zool. Stud. 8: 1942-46.
SANTE (2019). Accessed on 14/10/2022. https://www.eurl-pesticides.eu/userfiles/file/EurlALL/AqcGuidance_SANTE_2019_12682.pdf.
Uddin, F. M. Jamil, Molla  Ab Razzak, Rashid  Md. Harun, Sarkar  Shubroto Kumar, Karim Md Masudul, Akondo Md Robiul Islam, Islam Md Ariful, Imran Shahin and Paul  Newton Chandra (2022). Influence of nitrogen levels on yield of French bean (Phaseolus vulgaris) under different irrigation regimes. Res. Crop. 23: 163-71.
Vijayasree, V., Bai, H., Naseema Beevi, S., Mathew, T. B., Kumar, V., George, T. and Xavier, G. (2013). Persistence and effects of processing on reduction of chlorantraniliprole residues on cowpea fruits. Bull Environ Contam Toxicol. 90: 494-98.

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